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dc.contributor.authorBruce, Michael I.
dc.contributor.authorMatisons, Janis G.
dc.contributor.authorNicholson, Brian K.
dc.date.accessioned2010-10-31T22:50:17Z
dc.date.available2010-10-31T22:50:17Z
dc.date.issued1983
dc.identifier.citationBruce, M.I., Matisons, J.G. & Nicholson, B.K. (1983). Cluster Chemistry : XVII.Radical ion-initiated synthesis of ruthenium cluster carbonyls containing tertiary phosphines, phosphites, arsines, SbPh₃, or isocyanides. Journal of Organometallic Chemistry, 247(3), 321-343.en_NZ
dc.identifier.urihttps://hdl.handle.net/10289/4731
dc.description.abstractThe syntheses of over sixty known and new derivatives of Ru₃(CO)₁₂ and H₄Ru₄(CO)₁₂ by substitution reactions initiated by sodium diphenylketyl are described. The range of ligands studied includes isocyanides, tertiary phosphines and phosphites, tertiary arsines and SbPh₃. The reactions are characterised by high degrees of specificity and conversion: under mild conditions up to four ligands can be introduced. Comparisons with the corresponding thermally induced reactions are made in several cases. The reactions provide routes to mixed ligand derivatives of the cluster carbonyls, although account of relative Lewis base strengths of the ligands may have to be taken. Possible mechanisms of these reactions are discussed briefly, as are the IR ν (CO) spectra of the Ru₃ (CO)12-nLn complexes.en_NZ
dc.language.isoen
dc.publisherElsevieren_NZ
dc.subjectchemistryen_NZ
dc.titleCluster Chemistry : XVII.Radical ion-initiated synthesis of ruthenium cluster carbonyls containing tertiary phosphines, phosphites, arsines, SbPh₃, or isocyanidesen_NZ
dc.typeJournal Articleen_NZ
dc.identifier.doi10.1016/0022-328X(83)85174-2en_NZ


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