| dc.contributor.author | Duffy, D. Neil | |
| dc.contributor.author | Mackay, Kenneth M. | |
| dc.contributor.author | Nicholson, Brian K. | |
| dc.contributor.author | Robinson, Ward T. | |
| dc.date.accessioned | 2010-11-01T03:26:11Z | |
| dc.date.available | 2010-11-01T03:26:11Z | |
| dc.date.issued | 1981 | |
| dc.identifier.citation | Duffy, D.N., Mackay, K.M., Nicholson, B.K. & Robinson, W.T. (1981). Preparation and the crystal and molecular structure of [Net₄][Ge{Co₂(CO)₇}{Co₂(CO)₆[HgCo(CO)₄]}]: an anion containing a mercury-bridged cobalt–cobalt bond. Journal of the Chemical Society, Dalton Transactions, 2, 381-384. | en_NZ |
| dc.identifier.uri | https://hdl.handle.net/10289/4732 | |
| dc.description.abstract | The title compound has been isolated from the reaction of Gel4 with Na[Co(CO)₄] in the presence of Hg and has been characterised by X-ray analysis. Crystals are triclinic, a= 12.065(1), b= 17.334(2), c= 9.222(1)Å, α= 95.17(3), β= 82.72(3), γ= 96.95(3)°, space group P , and Z= 2. The structure has been solved by direct methods and refined to R= 0.049 for 3 136 reflections [I 5σ(I)]. The anion contains a common Ge atom bridging the Co–Co bonds both of a Co₂(CO)₇ unit and of a Co₂(CO)₆ unit which is also bridged by a HgCo(CO)₄ group. | en_NZ |
| dc.language.iso | en | |
| dc.relation.uri | http://pubs.rsc.org/en/Content/ArticleLanding/1981/DT/DT9810000381 | en_NZ |
| dc.subject | chemistry | en_NZ |
| dc.title | Preparation and the crystal and molecular structure of [Net₄][Ge{Co₂(CO)₇}{Co₂(CO)₆[HgCo(CO)₄]}]: an anion containing a mercury-bridged cobalt–cobalt bond | en |
| dc.type | Journal Article | en_NZ |
| dc.identifier.doi | 10.1039/DT9810000381 | en_NZ |
