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dc.contributor.authorAlblawi, Jamal
dc.contributor.authorHenderson, William
dc.contributor.authorNicholson, Brian K.
dc.date.accessioned2011-03-01T02:31:45Z
dc.date.available2011-03-01T02:31:45Z
dc.date.issued2011
dc.identifier.citationAlblawi, J., Henderson, W. & Nicholson, B.K. (2011). Synthesis and characterization of nickel(II) maltolate complexes containing ancillary bisphosphine ligands. Journal of Coordination Chemistry, 64(4), 679-687.en_NZ
dc.identifier.urihttps://hdl.handle.net/10289/5111
dc.description.abstractCationic nickel(II) complexes containing chelating O,O'-donor maltolate or ethyl maltolate ligands in conjunction with bidentate bisphosphine ligands Ph₂P(CH₂)nPPh₂ were prepared by a one-pot reaction starting from nickel(II) acetate, bisphosphine, maltol (or ethyl maltol), and trimethylamine, and isolated as their tetraphenylborate salts. An X-ray structure determination of [Ni(maltolate)(Ph₂PCH₂CH₂PPh₂)]BPh₄ shows that the maltolate ligand binds asymmetrically to the (slightly distorted) square-planar nickel(II) center. The simplicity of the synthetic method was extended to the synthesis of the known platinum(II) maltolate complex [Pt(maltolate)(PPh₃)₂]BPh₄ which was obtained in high purity.en_NZ
dc.format.mimetypeapplication/pdf
dc.language.isoen
dc.publisherTaylor & Francis Groupen_NZ
dc.relation.urihttp://www.informaworld.com/smpp/content~content=a933046578~db=all~jumptype=rssen_NZ
dc.rightsThis is a preprint of an article whose final and definitive form has been published in the Journal of Coordination Chemistry © 2011 copyright Taylor & Francis; Journal of Coordination Chemistry is available online at: www.tandfonline.com with the open URL of your article http://www.tandfonline.com/openurl?genre=article&issn=0095-8972&volume=64&issue=4&spage=679.
dc.subjectnickel complexesen_NZ
dc.subjectmaltol complexesen_NZ
dc.subjectphosphine ligandsen_NZ
dc.subjectX-ray crystal structureen_NZ
dc.titleSynthesis and characterization of nickel(II) maltolate complexes containing ancillary bisphosphine ligandsen_NZ
dc.typeJournal Articleen_NZ
dc.identifier.doi10.1080/00958972.2011.553224en_NZ
dc.relation.isPartOfJournal of Coordination Chemistryen_NZ
pubs.begin-page679en_NZ
pubs.elements-id35732
pubs.end-page687en_NZ
pubs.issue4en_NZ
pubs.volume64en_NZ
uow.identifier.article-noPII 933046578en_NZ


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