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      On the importance of π–π stacking and cation–anion interactions in the construction of non-centrosymmetric networks of bromide salts of imidazolium cations bearing arene and polyfluoroarene rings

      Saunders, Graham C.
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      Research Commons GCS 2.pdf
      Accepted version, 559.5Kb
      DOI
       10.1039/C1CE00003A
      Link
       pubs.rsc.org
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      Citation
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      Saunders, G.C. (2011). On the importance of π–π stacking and cation–anion interactions in the construction of non-centrosymmetric networks of bromide salts of imidazolium cations bearing arene and polyfluoroarene rings. CrystEngComm, 13, 1801-1803.
      Permanent Research Commons link: https://hdl.handle.net/10289/5206
      Abstract
      The salt 1-(2,3,5,6-tetrafluoropyridyl)-3-benzylimidazolium bromide crystallizes in the non-centrosymmetric space group Pna2₁. The structure arises from π–π stacking between the benzyl and tetrafluoropyridyl groups of the cations and cation–bromide interactions. It is the latter that gives rise to the non-centrosymmetry.
      Date
      2011
      Type
      Journal Article
      Publisher
      Royal Society of Chemistry
      Rights
      This is an author’s accepted version of an article published in the journal: CrystEngComm. © 2011 Royal Society of Chemistry.
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      • Science and Engineering Papers [3122]
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