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      New Sb₁₂ and Sb₁₄ Polyoxometalate Frameworks Derived from Arylstibonic Acids: [LiH₃(p-MeC₆H₄Sb)₁₂O₂₈]⁴⁻ and [BaH₁₀(p-MeC₆H₄Sb)₁₄O₃₄]

      Nicholson, Brian K.; Clark, Christopher J.; Wright, Cody Elvin; Telfers, Shane G.; Groutso, Tania
      DOI
       10.1021/om200739a
      Link
       pubs.acs.org
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      Citation
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      Nicholson, B.K., Clark, C.J., Wright, C.E., Telfers, S.G. & Groutso, T. (2011). New Sb₁₂ and Sb₁₄ Polyoxometalate Frameworks Derived from Arylstibonic Acids: [LiH₃(p-MeC₆H₄Sb)₁₂O₂₈]⁴⁻ and [BaH₁₀(p-MeC₆H₄Sb)₁₄O₃₄]. Organometallics, 30(24), 6612-6616.
      Permanent Research Commons link: https://hdl.handle.net/10289/5978
      Abstract
      The lithium salt of p-tolylstibonic acid contains the anion [LiH₃(p-MeC₆H₄Sb)₁₂O₂₈]⁴⁻, in which the Li⁺ is fully enclosed within an {Sb₁₂O₂₈} cage with γ Keggin ion geometry; the idealized overall formula is Li₅[LiH₃(p-MeC₆H₄Sb)₁₂O₂₈]Br•18H₂O. In contrast, Ba²⁺ induces the formation of the unprecedented {Sb₁₄O₃₄} bowl-shaped polyoxostibonate [BaH₁₀(p-MeC₆H₄Sb)₁₄O₃₄]•4H₂O. Compounds were characterized by single-crystal X-ray crystallography and by ESI-MS.
      Date
      2011
      Type
      Journal Article
      Publisher
      American Chemistry Society
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      • Science and Engineering Papers [3073]
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