Research Commons
      • Browse 
        • Communities & Collections
        • Titles
        • Authors
        • By Issue Date
        • Subjects
        • Types
        • Series
      • Help 
        • About
        • Collection Policy
        • OA Mandate Guidelines
        • Guidelines FAQ
        • Contact Us
      • My Account 
        • Sign In
        • Register
      View Item 
      •   Research Commons
      • University of Waikato Research
      • Science and Engineering
      • Science and Engineering Papers
      • View Item
      •   Research Commons
      • University of Waikato Research
      • Science and Engineering
      • Science and Engineering Papers
      • View Item
      JavaScript is disabled for your browser. Some features of this site may not work without it.

      Polarized Complexes Obtained by Regiospecific Substitution of a CN Group in Ru{C≡CC(CN)═C(CN)₂}(dppe)Cp* (Cp* = η-C₅Me₅)

      Bruce, Michael I.; Burgun, Alexandre; Nicholson, Brian K.; Parker, Christian R.; Skelton, Brian W.; White, Allan H.
      DOI
       10.1021/om300059q
      Link
       pubs.acs.org
      Find in your library  
      Citation
      Export citation
      Bruce, M.I., Burgun, A., Nicholson, B.K., Parker, C.R., Skelton, B.W. & White, A.H. (2012). Polarized Complexes Obtained by Regiospecific Substitution of a CN Group in Ru{C≡CC(CN)═C(CN)₂}(dppe)Cp* (Cp* = η-C₅Me₅). Organometallics, 31(11), 4174-4181.
      Permanent Research Commons link: https://hdl.handle.net/10289/6435
      Abstract
      The complex Ru{C≡CC(CN)═C(CN)₂}(dppe)Cp* (1), containing the new tricyanovinylethynyl (3,4,4-tricyanobut-3-en-1-ynyl) ligand, undergoes ready substitution of the 3-cyano group by nucleophiles (Nu) such as H, Me, Pri, Bu, But, mesityl, OMe, OBut, OCH2CH═CH₂, NHEt, NEt₂, and PPh₂ to give Ru{C≡CC(Nu)═C(CN)₂}(dppe)Cp*. The X-ray diffraction structures of several of the resulting complexes are reported and, for the mesityl and PPh₂ products, show that isomerization to the 3,5-dimethylbenzyl and oxidation to the phosphine oxide have respectively occurred.
      Date
      2012
      Type
      Journal Article
      Publisher
      American Chemistry Society
      Collections
      • Science and Engineering Papers [3122]
      Show full item record  

      Usage

       
       
       

      Usage Statistics

      For this itemFor all of Research Commons

      The University of Waikato - Te Whare Wānanga o WaikatoFeedback and RequestsCopyright and Legal Statement