| dc.contributor.author | Bruce, Michael I. | |
| dc.contributor.author | Burgun, Alexandre | |
| dc.contributor.author | Nicholson, Brian K. | |
| dc.contributor.author | Parker, Christian R. | |
| dc.contributor.author | Skelton, Brian W. | |
| dc.contributor.author | White, Allan H. | |
| dc.date.accessioned | 2012-07-02T02:27:07Z | |
| dc.date.available | 2012-07-02T02:27:07Z | |
| dc.date.copyright | 2012-06-11 | |
| dc.date.issued | 2012 | |
| dc.identifier.citation | Bruce, M.I., Burgun, A., Nicholson, B.K., Parker, C.R., Skelton, B.W. & White, A.H. (2012). Polarized Complexes Obtained by Regiospecific Substitution of a CN Group in Ru{C≡CC(CN)═C(CN)₂}(dppe)Cp* (Cp* = η-C₅Me₅). Organometallics, 31(11), 4174-4181. | en_NZ |
| dc.identifier.uri | https://hdl.handle.net/10289/6435 | |
| dc.description.abstract | The complex Ru{C≡CC(CN)═C(CN)₂}(dppe)Cp* (1), containing the new tricyanovinylethynyl (3,4,4-tricyanobut-3-en-1-ynyl) ligand, undergoes ready substitution of the 3-cyano group by nucleophiles (Nu) such as H, Me, Pri, Bu, But, mesityl, OMe, OBut, OCH2CH═CH₂, NHEt, NEt₂, and PPh₂ to give Ru{C≡CC(Nu)═C(CN)₂}(dppe)Cp*. The X-ray diffraction structures of several of the resulting complexes are reported and, for the mesityl and PPh₂ products, show that isomerization to the 3,5-dimethylbenzyl and oxidation to the phosphine oxide have respectively occurred. | en_NZ |
| dc.language.iso | en | |
| dc.publisher | American Chemistry Society | en_NZ |
| dc.relation.ispartof | Organometallics | |
| dc.relation.uri | http://pubs.acs.org/doi/abs/10.1021/om300059q | en_NZ |
| dc.subject | chemistry | en_NZ |
| dc.title | Polarized Complexes Obtained by Regiospecific Substitution of a CN Group in Ru{C≡CC(CN)═C(CN)₂}(dppe)Cp* (Cp* = η-C₅Me₅) | en_NZ |
| dc.type | Journal Article | en_NZ |
| dc.identifier.doi | 10.1021/om300059q | en_NZ |
| dc.relation.isPartOf | Organometallics | en_NZ |
| pubs.begin-page | 4174 | en_NZ |
| pubs.elements-id | 37674 | |
| pubs.end-page | 4181 | en_NZ |
| pubs.issue | 11 | en_NZ |
| pubs.volume | 31 | en_NZ |
