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dc.contributor.authorNair, Ashwin Gopalan
dc.contributor.authorUjam, Oguejiofo Theophilus
dc.contributor.authorLane, Joseph R.
dc.contributor.authorHenderson, William
dc.contributor.authorNicholson, Brian K.
dc.date.accessioned2012-10-30T01:14:07Z
dc.date.available2012-10-30T01:14:07Z
dc.date.copyright2012-11-10
dc.date.issued2012
dc.identifier.citationNair, A. G., Ujam, O. T., Lane, J. R., Henderson, W., & Nicholson, B. K. (2012). Platinum(II) complexes containing the 3,3-dimethylglutarimidate ligand. Journal of Coordination Chemistry, 65(21), 3731-3739.en_NZ
dc.identifier.issn0095-8972
dc.identifier.urihttps://hdl.handle.net/10289/6761
dc.description.abstractReaction of cis-[PtCl ₂(PPh ₃) ₂] with excess 3,3-dimethylglutarimide (dmgH) and sodium chloride in refluxing methanol gives the mono-imidate complex cis-[PtCl(dmg)(PPh ₃) ₂], which was structurally characterized. The plane of the imidate ligand is approximately perpendicular to the platinum coordination plane which, coupled with restricted rotation about the Pt-N bond, results in inequivalent methyl groups and CH2 protons of the dmg ligand in the room temperature ¹H NMR spectrum. These observations were corroborated by a theoretical study using density functional theory methods. The analogous bromide complex cis-[PtBr(dmg)(PPh ₃) ₂] can be prepared by replacing NaCl with NaBr in the reaction mixture.en_NZ
dc.language.isoen
dc.publisherTaylor & Francisen_NZ
dc.relation.ispartofJournal of Coordination Chemistry
dc.subjectCrystal structureen_NZ
dc.subjectImidate complexesen_NZ
dc.subjectPlatinum complexesen_NZ
dc.subjectTheoretical calculationsen_NZ
dc.titlePlatinum(II) complexes containing the 3,3-dimethylglutarimidate liganden_NZ
dc.typeJournal Articleen_NZ
dc.identifier.doi10.1080/00958972.2012.722627en_NZ
dc.relation.isPartOfJournal of Coordination Chemistryen_NZ
pubs.begin-page3731en_NZ
pubs.elements-id38057
pubs.end-page3739en_NZ
pubs.issue21en_NZ
pubs.volume65en_NZ


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