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dc.contributor.authorNieuwenhuyzen, Mark
dc.contributor.authorSaunders, Graham C.
dc.date.accessioned2013-05-07T03:14:22Z
dc.date.available2013-05-07T03:14:22Z
dc.date.copyright2013-02-26
dc.date.issued2013
dc.identifier.citationNieuwenhuyzen, M., & Saunders, G. C. (2013). Crystal structure of (η5-pentamethylcyclo-pentadienyl)(methyldiphenylphosphite-P)dichlororhodium(III). Journal of Structural Chemistry, 54(1), 264-268.en_NZ
dc.identifier.issn0022-4766
dc.identifier.urihttps://hdl.handle.net/10289/7586
dc.description.abstractThe molecule (η⁵-pentamethylcyclopentadienyl)(methyldiphenylphosphinite-P)dichlororhodium(III), [(η⁵-C₅Me₅)RhCl₂(PPh₂OMe)], crystallizes in the monoclinic crystal system in space group P2₁/c with unit cell parameters a = 16.056(3) Å, b = 9.4331(18) Å, c = 15.745(3) Å, β = 108.330(4), V = 2263.8(7) ų and Z = 4. There is three-legged piano stool geometry about Rh. The Rh-P distance of 2.278(2) Å is shorter than those of [(η⁵-C₅Me₅)RhCl₂(PPh₂OR)] where R is an aryl group, and longer than those found in [(η⁵-C₅Me₅)RhCl₂{PPh(OR)₂}]. The structure reveals significant distortion of the pentamethylcyclopentadienyl towards ′η³,η²-enyl-ene′ coordination.en_NZ
dc.language.isoen
dc.publisherSpringer-Verlagen_NZ
dc.relation.ispartofJournal of Structural Chemistry
dc.subjectη⁵-pentamethylcyclopentadienylen_NZ
dc.subjectring slippageen_NZ
dc.subjectrhodiumen_NZ
dc.subjectX-ray structureen_NZ
dc.titleCrystal structure of (η⁵-pentamethylcyclo-pentadienyl)(methyldiphenylphosphite-P)dichlororhodium(III)en_NZ
dc.typeJournal Articleen_NZ
dc.identifier.doi10.1134/S0022476613010411en_NZ
dc.relation.isPartOfJournal of Structural Chemistryen_NZ
pubs.begin-page264en_NZ
pubs.elements-id38372
pubs.end-page268en_NZ
pubs.issue1en_NZ
pubs.volume54en_NZ


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