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dc.contributor.authorSaunders, Graham C.
dc.date.accessioned2013-08-05T04:56:46Z
dc.date.available2013-08-05T04:56:46Z
dc.date.copyright2013-05
dc.date.issued2013
dc.identifier.citationSaunders, G. C. (2013). Short Intermolecular Phosphorus…Phosphorus Distances in the Crystal Structures of Bis{Bis(Perfluoroaryl)Phosphino}Methanes. Phosphorus, Sulfur, and Silicon and the Related Elements, 188(5), 525-538.en_NZ
dc.identifier.urihttps://hdl.handle.net/10289/7820
dc.description.abstractThe crystal structure of bis{bis(4-trifluoromethyltetrafluorophenyl)phosphino}-methane 2 determined by single crystal X-ray diffraction comprises pairs of molecules related by an inversion center and possessing short P•••P distances. The molecular structure and the structure of the pairs are similar to those in the crystal structure of bis{bis(pentafluorophenyl)-phosphino}methane, although the packing is different. Comparison with the structures of bis(diphenylphosphino)methane and bis{bis(pentafluorophenyl)phosphine}difluoromethane suggests that intramolecular C–H•••F–C interactions are the most important factor in determining the presence of the short P•••P distances in the crystal structures of bis(diarylphosphino)methanes.en_NZ
dc.language.isoenen_NZ
dc.publisherTaylor & Francisen_NZ
dc.relation.ispartofPhosphorus, Sulfur, and Silicon and the Related Elements
dc.relation.urihttp://www.tandfonline.com/doi/full/10.1080/10426507.2012.700353#.Uf8traz4J7sen_NZ
dc.subjectBis{bis(4-trifluoromethyltetrafluorophenyl)phosphino}methaneen_NZ
dc.subjectcrystal structureen_NZ
dc.subjectP•••P contacten_NZ
dc.titleShort Intermolecular Phosphorus…Phosphorus Distances in the Crystal Structures of Bis{Bis(Perfluoroaryl)Phosphino}Methanesen_NZ
dc.typeJournal Articleen_NZ
dc.identifier.doi10.1080/10426507.2012.700353en_NZ
dc.relation.isPartOfPhosphorus, Sulfur, and Siliconen_NZ
pubs.begin-page525en_NZ
pubs.elements-id38510
pubs.end-page538en_NZ
pubs.issue5en_NZ
pubs.volume188en_NZ


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