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dc.contributor.authorSmith, Tiffany Sharee
dc.contributor.authorHenderson, William
dc.contributor.authorNicholson, Brian K.
dc.date.accessioned2013-12-12T22:19:37Z
dc.date.available2013-12-12T22:19:37Z
dc.date.copyright2013-11
dc.date.issued2013-11
dc.identifier.citationSmith, T. S., Henderson, W., & Nicholson, B. K. (2013). Cycloaurated gold(III) complexes with monoanionic thiourea ligands. Inorganica Chimica Acta, 408, 27-32.en_NZ
dc.identifier.urihttps://hdl.handle.net/10289/8343
dc.description.abstractUsing a simple one-pot procedure, reaction of cycloaurated gold(III) dihalide complexes [LAuCl₂] (L = 2-benzylpyridyl, 2-anilinopyridyl) with trisubstituted thioureas PhNHC(S)NR₂ (R = Me, Cy) and Me3N in methanol, followed by addition of excess NaBPh₄ gave the salts [Lau{SC(-NR₂)NPh}]⁺BPH₄⁻ containing N,S-chelated thiourea monoanion ligands. The compounds were obtained in good yields, and were characterised by ESI MS, elemental microanalysis and in two cases by X-ray structure determinations. The series of complexes was extended by additional microscale reactions of LAuCl₂ complexes (L = 2-benzylpyridyl, 2-anilinopyridyl, 2-benzoylpyridyl or picolinamide) with a wide range of trisubstituted thioureas, with products identified by ESI MS.en_NZ
dc.language.isoenen_NZ
dc.publisherElsevieren_NZ
dc.relation.ispartofInorganica Chimica Acta
dc.relation.urihttp://www.sciencedirect.com/science/article/pii/S0020169313003988en_NZ
dc.subjectgold complexesen_NZ
dc.subjectthiourea liganden_NZ
dc.subjectcycloaurated complexesen_NZ
dc.subjectcrystal structureen_NZ
dc.subjectelectrospray ionisation mass spectrometryen_NZ
dc.titleCycloaurated gold(III) complexes with monoanionic thiourea ligandsen_NZ
dc.typeJournal Articleen_NZ
dc.identifier.doi10.1016/j.ica.2013.07.027en_NZ
dc.relation.isPartOfInorganica Chimica Actaen_NZ
pubs.begin-page27en_NZ
pubs.elements-id38973
pubs.end-page32en_NZ
pubs.volume408en_NZ
uow.identifier.article-noCen_NZ


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