In this study, the effects of interleaved nanofibre veils on the Mode I and Mode II interlaminar fracture toughness (ILFT) of autoclave cured unidirectional carbon/epoxy composite laminates were investigated. Various electrospun nanofibre veils consisting of a range of different polymer types, fibre diameters and veil architectures were placed in the laminate mid-planes, which were subsequently subjected to double cantilever beam and end-notch flexure tests. It was found that the polymer type and veil areal weight were the most important factors contributing to laminate performance. A 4.5 g/m2 PA66 veil provided the best all-round performance with fracture toughness improvements of 156% and 69% for Mode I and Mode II, respectively.