Item

Complexes of η⁵, κP-cyclopentadienyl-phosphine ligands by chelate-assisted dehydrofluorinative coupling; the coupling of bis{bis(pentafluorophenyl)phosphino}methane to η⁵-pentamethylcyclopentadienyl in a rhodium complex

Abstract
The reaction between [{(η⁵-C₅Me₅)RhCl(μ-Cl)}₂] and (C₆F₅)₂PCH₂P(C₆F₅)₂ in refluxing benzene yields the singly linked complex [{(η⁵,κP-C₅Me₄ CH₂C₆F₄-2-P(C₆F₅)CH₂P(C₆F₅)₂)}RhCl₂] in which only one phosphorus atom is coordinated to the rhodium.
Type
Journal Article
Type of thesis
Series
Citation
Marr, A.C., Nieuwenhuyzen, M., Pollock, C.L., Saunders, G.C. (2006). Complexes of η⁵, κP-cyclopentadienyl-phosphine ligands by chelate-assisted dehydrofluorinative coupling; the coupling of bis{bis(pentafluorophenyl)phosphino}methane to η⁵-pentamethylcyclopentadienyl in a rhodium complex. Inorganic Chemistry Communications, 9(4), 407-409.
Date
2006
Publisher
Elsevier
Degree
Supervisors
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