Synthesis and structure of the amidate-bridged platinum-uranium bimetallic complex [Pt{NC(O)CH₂CH₂}₂(PPh₃)₂].UO₂(NO₃)₂

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dc.contributor.authorHenderson, William
dc.contributor.authorOliver, Allen G.
dc.contributor.authorRickard, Clifton E.F.
dc.date.accessioned2009-11-26T20:19:08Z
dc.date.available2009-11-26T20:19:08Z
dc.date.issued2000
dc.description.abstractThe reaction of the β-propiolactam-derived platinum(II) amidate complex [Pt{NC(O)CH₂CH₂}₂(PPh₃)₂]with uranyl nitrate gives the coordination complex [Pt{NC(O)CH₂CH₂}₂(PPh₃)₂].UO₂(NO₃)₂, which was characterised by a single-crystal X-ray diffraction study. The lactam carbonyl groups are coordinated to the linear uranyl group, forming an eight-membered ring, with the uranium also having two bidentate nitrates, completing a hexagonal bipyramidal coordination geometry. The platinum and uranium coordination planes are almost perpendicular, at an angle of 85.4(1)°.en
dc.identifier.citationHenderson, W., Oliver, A. G., & Rickard, C. E. F. (2000). Synthesis and structure of the amidate-bridged platinum-uranium bimetallic complex [Pt{NC(O)CH₂CH₂}₂(PPh₃)₂].UO₂(NO₃)₂. Inorganica Chimica Acta, 307(1/2), 144-148.en
dc.identifier.doi10.1016/S0020-1693(00)00186-9en
dc.identifier.urihttps://hdl.handle.net/10289/3421
dc.language.isoen
dc.publisherELSEVIER SCIENCE SAen_NZ
dc.relation.isPartOfInorganica Chimica Actaen_NZ
dc.subjectcrystal structuresen
dc.subjectplatinum complexesen
dc.subjecturanium complexesen
dc.subjectlactam complexesen
dc.subjectbimetallic complexesen
dc.titleSynthesis and structure of the amidate-bridged platinum-uranium bimetallic complex [Pt{NC(O)CH₂CH₂}₂(PPh₃)₂].UO₂(NO₃)₂en
dc.typeJournal Articleen
pubs.begin-page144en_NZ
pubs.elements-id41516
pubs.end-page148en_NZ
pubs.issue1-2en_NZ
pubs.volume307en_NZ
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