Orthomercurated and cycloaurated derivatives of the iminophosphorane Ph3P NPh

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dc.contributor.authorBrown, Samuel D.J.en_US
dc.contributor.authorHenderson, Williamen_US
dc.contributor.authorKilpin, Kelly Joanen_US
dc.contributor.authorNicholson, Brian K.en_US
dc.date.accessioned2008-03-19T05:11:09Z
dc.date.available2007-09-02en_US
dc.date.available2008-03-19T05:11:09Z
dc.date.issued2007-03-01en_US
dc.description.abstractOrtho-lithiation of Ph3P NPh followed by reaction with HgCl2 gave good yields of [Hg{C6H4(PPh2 NPh)-2}Cl], 3, which was characterised spectroscopically and by an X-ray crystal structure determination. This is an isomer of the product of direct mercuration of Ph3P NPh which occurs on the N-bonded phenyl ring [J. Vicente, J.A. Abad, R. Clemente, J. Lopez-Serrano, M.C. Ramirez de Arellano, P.G. Jones, D. Bautista, Organometallics, 22 (2003) 4248]. Transmetallation of 3 with [AuCl4]− gave the corresponding cycloaurated complex [Au{κ2-C,N-C6H4(PPh2 NPh)-2}Cl2], with a five-membered metallocyclic ring incorporating four different elements.en_US
dc.format.mimetypeapplication/pdf
dc.identifier.citationBrown, S. D. J., Henderson, W., Kilpin, K.J. & Nicholson, B.K. (2007). Orthomercurated and cycloaurated derivatives of the iminophosphorane Ph3P NPh. Inorganica Chimica Acta, 360, 1310-15.en_US
dc.identifier.doi10.1016/j.ica.2006.02.009en_US
dc.identifier.urihttps://hdl.handle.net/10289/181
dc.language.isoen
dc.publisherElsevier BVen_NZ
dc.relation.isPartOfInorganica Chimica Actaen_NZ
dc.relation.urihttp://www.elsevier.com/wps/find/journaldescription.cws_home/504086/description#descriptionen_US
dc.rightsThis is an authors version of an article published in the journal, Inorganica Chimica Acta, (c) 2006 Elsevier B.V.en_US
dc.subjectIminiphosphoraneen_US
dc.subjectmercurateden_US
dc.subjectcycloaurateden_US
dc.subjectx-ray crystal structuresen_US
dc.titleOrthomercurated and cycloaurated derivatives of the iminophosphorane Ph3P NPhen_US
dc.typeJournal Articleen_US
pubs.begin-page1310en_NZ
pubs.editionMarchen_NZ
pubs.elements-id32492
pubs.end-page1315en_NZ
pubs.issue4en_NZ
pubs.volume360en_NZ
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