Synthesis and characterisation of organo-platinum(II) complexes of the N,O-donor ligands hippuric acid (N-benzoylglycine) and N-phenylanthranilic acid

Simple item page
dc.contributor.authorSim, Sophie A.en_NZ
dc.contributor.authorSaunders, Graham C.en_NZ
dc.contributor.authorLane, Joseph R.en_NZ
dc.contributor.authorHenderson, Williamen_NZ
dc.date.accessioned2018-08-20T01:43:08Z
dc.date.available2016-08-24en_NZ
dc.date.available2018-08-20T01:43:08Z
dc.date.issued2016en_NZ
dc.description.abstractReaction of [PtCl₂(cod)] (cod = cyclo-octa-1,5-diene) with either hippuric acid [PhC(O)NHCH₂COOH] or N-phenylanthranilic acid (ortho-PhNHC₆H₄COOH) in refluxing dichloromethane in the presence of silver(I) oxide gave the new organoplatinum derivatives [Pt{N(COPh)CH₂COO}(cod)] and [Pt{N(Ph)C₆H₄COO}(cod)] respectively. Ligand substitution reactions of the cod ligand in [Pt{N(COPh)CH₂COO}(cod)] provided a facile route to a selection of phosphine-substituted analogues [Pt{N(COPh)CH₂COO}L₂] [L = phosphatriazaadamantane (pta), PPh3, or L₂ = Ph₂PCH₂CH₂PPh₂ or Fe(η⁵-C₅H₄PPh₂) ₂] via displacement of the labile cod ligand. The complexes were characterised using NMR spectroscopy, IR spectroscopy, and ESI mass spectrometry. The X-ray structure of [Pt{N(COPh)CH₂COO}(cod)] is also reported.
dc.format.mimetypeapplication/pdf
dc.identifier.citationSim, S. A., Saunders, G. C., Lane, J. R., & Henderson, W. (2016). Synthesis and characterisation of organo-platinum(II) complexes of the N,O-donor ligands hippuric acid (N-benzoylglycine) and N-phenylanthranilic acid. Inorganica Chimica Acta, 450, 285–292. https://doi.org/10.1016/j.ica.2016.05.053en
dc.identifier.doi10.1016/j.ica.2016.05.053en_NZ
dc.identifier.eissn1873-3255en_NZ
dc.identifier.issn0020-1693en_NZ
dc.identifier.urihttps://hdl.handle.net/10289/12025
dc.language.isoenen_NZ
dc.publisherElsevieren_NZ
dc.relation.isPartOfInorganica Chimica Actaen_NZ
dc.rightsThis is an author’s accepted version of an article published in the journal: Inorganica Chimica Acta. © 2016 Elsevier.
dc.subjectScience & Technologyen_NZ
dc.subjectPhysical Sciencesen_NZ
dc.subjectChemistry, Inorganic & Nuclearen_NZ
dc.subjectChemistryen_NZ
dc.subjectPlatinum complexesen_NZ
dc.subjectMetallacyclic complexesen_NZ
dc.subjectSilver(I) oxideen_NZ
dc.subjectHippuric aciden_NZ
dc.subjectN-Phenylanthranilic aciden_NZ
dc.subjectCrystal structureen_NZ
dc.subjectRARE-EARTH COMPLEXESen_NZ
dc.subjectAMINO-ACIDSen_NZ
dc.subjectCRYSTAL-STRUCTUREen_NZ
dc.subjectORGANOMETALLIC COMPLEXESen_NZ
dc.subjectRHODIUM(I) COMPLEXESen_NZ
dc.subjectPLATINUM COMPLEXESen_NZ
dc.subjectMETAL-COMPLEXESen_NZ
dc.subjectPALLADIUM(II)en_NZ
dc.subjectREACTIVITYen_NZ
dc.subjectDERIVATIVESen_NZ
dc.titleSynthesis and characterisation of organo-platinum(II) complexes of the N,O-donor ligands hippuric acid (N-benzoylglycine) and N-phenylanthranilic aciden_NZ
dc.typeJournal Article
pubs.begin-page285
pubs.declined2016-06-27T16:51:01.908+1200
pubs.elements-id139478
pubs.end-page292
pubs.organisational-group/Waikato
pubs.organisational-group/Waikato/2018 PBRF
pubs.organisational-group/Waikato/FSEN
pubs.organisational-group/Waikato/FSEN/2018 PBRF - FSEN
pubs.organisational-group/Waikato/FSEN/School of Science
pubs.organisational-group/Waikato/FSEN/School of Science/2018 PBRF - School of Science
pubs.publication-statusPublisheden_NZ
pubs.user.infoSaunders, Graham (gsaunder@waikato.ac.nz)
pubs.user.infoLane, Joseph (jlane@waikato.ac.nz)
pubs.user.infoHenderson, William (hende@waikato.ac.nz)
pubs.volume450en_NZ
uow.verification.statusverified
Files
Original bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
document (4).pdf
Size:
774.1 KB
Format:
Adobe Portable Document Format
Description:
Accepted version
Name: document (4).pdf
Size: 774.1 KB
Kind: Adobe PDF
License bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
Research Commons Deposit Agreement 2017.pdf
Size:
188.11 KB
Format:
Adobe Portable Document Format
Description:
Name: Research Commons Deposit Agreement 2017.pdf
Size: 188.11 KB
Kind: Adobe PDF
Collections
Science and Engineering Papers