On the precipitability of binary Ti alloys bearing 4-period d-metal eutectoid stabilisers

Abstract

There is no specific, simple approach for predicting whether the addition of an eutectoid beta stabiliser to Ti leads to an ‘active’ eutectoid transformation upon primary processing (e.g., sintering). Here, we demonstrate that, among theoretical/empirical models, phase diagram features, and electronic structure parameters, the hypoeutectoid area is the best predictor, followed by the molybdenum equivalent parameter (MoE), of the precipitability for 4-period d-metals. As the area increases, which corresponds to the addition of progressively stronger β-eutectoid stabilisers, the less active the eutectoid phase transformation, changing from pearlitic to bainitic (i.e., need for an ageing heat treatment). This occurs if the MoE weighted coefficient is, respectively, lower than or higher than 1. This is because molybdenum is taken as reference, and the higher the coefficient, the larger the drop of the β transus temperature (i.e., higher stabilisation). Valid for 4-period d-metals, it remains to be proven for 5-period and 6-period d-metals.