Synthesis of Poly(galactaramides) from Alkylene- and Substituted Alkylenediammonium Galactarates

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dc.contributor.authorKiely, Donald E.
dc.contributor.authorVishwanathan, Arvind
dc.contributor.authorJarman, Bevan P.
dc.contributor.authorManley-Harris, Merilyn
dc.date.accessioned2009-08-18T23:47:51Z
dc.date.available2009-08-18T23:47:51Z
dc.date.issued2009
dc.description.abstractPolyhydroxypolyamides (PHPAs) represent a class of synthetic polyamides derived from aldaric acid and diamine monomer units. This paper describes the synthesis of some poly(galactaramides), a class of polyhydroxypolyamides, that employs alkylene and substituted alkylenediammonium galactarate salts, with 1:1 molar equivalency of the diacid and diamine monomer components, as precursors for the polyamides. The salts were treated with acid/alcohol and then base in order to initiate the polymerization in methanol. The polyamides, labeled as prepolyamides, precipitated from solution and were then subjected to a second polymerization (postpolymerization) in a different solvent to produce a generally larger polyamide, labeled as a postpolyamide.en
dc.identifier.citationKiely, D. E., Vishwanathan, A., Jarman, B. P. & Manley-Harris, M. (2009). Synthesis of Poly(galactaramides) from Alkylene- and Substituted Alkylenediammonium Galactarates. Journal of Carbohydrate Chemistry, 28(6), 348-368.en
dc.identifier.doi10.1080/07328300903080749en
dc.identifier.urihttps://hdl.handle.net/10289/2845
dc.language.isoen
dc.publisherTaylor & Francis Groupen_NZ
dc.relation.isPartOfJournal of Carbohydrate Chemistryen_NZ
dc.relation.urihttp://www.informaworld.com/smpp/content~db=all~content=a913402739en
dc.subjectpolyamidesen
dc.subjectstructure-property relationshipen
dc.subjectPolyhydroxypolyamidesen
dc.subjectpoly(galactaramides)en
dc.titleSynthesis of Poly(galactaramides) from Alkylene- and Substituted Alkylenediammonium Galactaratesen
dc.typeJournal Articleen
pubs.begin-page348en_NZ
pubs.elements-id34262
pubs.end-page368en_NZ
pubs.issue6en_NZ
pubs.volume28en_NZ
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