A structural isomer of the [CoFe3(CO)13]− anion
dc.contributor.author | Evans, Cameron | en_US |
dc.contributor.author | Nicholson, Brian K. | en_US |
dc.date.accessioned | 2008-03-19T05:07:56Z | |
dc.date.available | 2007-11-21 | en_US |
dc.date.available | 2008-03-19T05:07:56Z | |
dc.date.issued | 2002-02-01 | en_US |
dc.description.abstract | The crystal structure of [Et4N][CoFe3 (CO) 13] has been determined, and shown to contain an anion with the CO ligands adopting a very different arrangement about the tetrahedral CoFe3 core to that found for the same anion, reported previously for the PPN+ salt. The relationship between the two structures can be understood in terms of Johnson's Ligand Polyhedral Model. In contrast the anion in [Et4N][CoRu3 (CO) 13] has the same geometry as that described in the corresponding PPN+ salt. | en_US |
dc.identifier.citation | Evans, C. & Nicholson, B.K. (2002). A structural isomer of the [CoFe3(CO)13]- anion. Journal of Organometallic Chemistry, 645(1-2), 281-285. | en_US |
dc.identifier.doi | 10.1016/S0022-328X(01)01356-0 | en_US |
dc.identifier.uri | https://hdl.handle.net/10289/223 | |
dc.language.iso | en | |
dc.publisher | Elsevier | en_NZ |
dc.relation.isPartOf | Journal of Organometallic Chemistry | en_NZ |
dc.relation.uri | http://www.sciencedirect.com.ezproxy.waikato.ac.nz:2048/science?_ob=ArticleURL&_udi=B6TGW-44NM240-3&_user=100025&_coverDate=02%2F15%2F2002&_rdoc=37&_fmt=full&_orig=browse&_srch=doc-info(%23toc%235265%232002%23993549998%23283812%23FLA%23display%23Volume)&_cdi=5265&_sort=d&_docanchor=&view=g&_ct=45&_acct=C000007699&_version=1&_urlVersion=0&_userid=100025&md5=e2018b0ba4ab7fb812bd54ba18fb2bfc | en_US |
dc.rights | This article is published in the Journal of Organometallic Chemistry, (c) 2002 Elsevier Science B.V. | en_US |
dc.subject | Cluster | en_US |
dc.subject | Isomer | en_US |
dc.subject | Polyhedral | en_US |
dc.subject | Iron | en_US |
dc.subject | Cobalt; X-ray structure | en_US |
dc.title | A structural isomer of the [CoFe3(CO)13]− anion | en_US |
dc.type | Journal Article | en_US |
pubs.begin-page | 281 | en_NZ |
pubs.edition | October | en_NZ |
pubs.elements-id | 27337 | |
pubs.end-page | 285 | en_NZ |
pubs.issue | 4 | en_NZ |
pubs.volume | 645 | en_NZ |