An orthomanganation route to 2-substituted derivatives of N-methyl-1,8-naphthalimide
dc.contributor.author | Nicholson, Brian K. | |
dc.contributor.author | Crosby, Paul M. | |
dc.contributor.author | Maunsell, Kieran R. | |
dc.contributor.author | Wyllie, Megan J. | |
dc.date.accessioned | 2012-10-03T03:03:56Z | |
dc.date.available | 2012-10-03T03:03:56Z | |
dc.date.copyright | 2012-10 | |
dc.date.issued | 2012 | |
dc.description.abstract | N-methyl naphthalimide can be readily cyclomanganated at the 2-position, directed by the adjacent amide O atom. Di-cyclomanganation also occurs readily to attach Mn(CO)₄ groups at both 2, 7 positions. An X-ray structure determination of the mono-substituted example confirmed the five-membered metallocyclic ring. Cleavage of the Mn–C bond by HgCl₂ or ICl generates 2-substituted HgCl or I derivatives respectively. Reaction of the mono-cyclomanganated N-methyl naphthalimide with phenylacetylene gives an (η⁵-cyclohexadienyl)Mn(CO)₃ complex where the cyclohexadienyl ring has formed by two PhCCH adding in a formal [2 + 2 + 2] process across the C(1)–C(2) bond of the naphthalimide, breaking the aromaticity of the naphthalene ring as shown by a single crystal structure determination. | en_NZ |
dc.identifier.citation | Nicholson, B. K., Crosby, P. M., Maunsell, K. R., & Wyllie, M. J. (2012). An orthomanganation route to 2-substituted derivatives of N-methyl-1,8-naphthalimide. Journal of Organometallic Chemistry, 716, 49-54. | en_NZ |
dc.identifier.doi | 10.1016/j.jorganchem.2012.06.035 | en_NZ |
dc.identifier.issn | 0022-328 | |
dc.identifier.uri | https://hdl.handle.net/10289/6675 | |
dc.language.iso | en | |
dc.publisher | Elsevier | en_NZ |
dc.relation.isPartOf | Journal of Organometallic Chemistry | en_NZ |
dc.relation.ispartof | Journal of Organometallic Chemistry | |
dc.subject | Naphthalimide | en_NZ |
dc.subject | Cyclometalation | en_NZ |
dc.subject | Manganese carbonyl | en_NZ |
dc.subject | X-ray crystal structure | en_NZ |
dc.subject | Alkyne | en_NZ |
dc.title | An orthomanganation route to 2-substituted derivatives of N-methyl-1,8-naphthalimide | en_NZ |
dc.type | Journal Article | en_NZ |
pubs.begin-page | 49 | en_NZ |
pubs.elements-id | 38060 | |
pubs.end-page | 54 | en_NZ |
pubs.volume | 716 | en_NZ |
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