Show simple item record  

dc.contributor.advisorSammes, Nigel
dc.contributor.authorHatchwell, Charles Edward
dc.date.accessioned2022-08-18T03:16:50Z
dc.date.available2022-08-18T03:16:50Z
dc.date.issued1999
dc.identifier.urihttps://hdl.handle.net/10289/15047
dc.description.abstractThe object of this thesis was to fabricate tubular solid oxide fuel cell (SOFC) systems operating with both high and medium temperature electrolytes, and then to study their electrical behaviour using various current collection methods. The research has demonstrated that yttria-stabilised zirconia (YSZ) and Ce₀.₈Gd₀.₂O₁.₉ tubular electrolytes can be used as a basis for fabricating excellent high thermal shock resistant, rapid start up SOFC systems. The feasibility of using current collection materials with the Ce₀.₈Gd₀.₂O₁.₉ electrolyte system at operational and co-firing temperatures has also been established via chemical compatibility studies. Three methods of cathode current collection were investigated. These included silver coatings applied as strips along the cathode, Nimonic 90 alloy wires, and grooved metal Cr5Fe1Y₂O₃ plates. Conductive coatings were applied to the surface of the Nimonic 90 wires and Cr5Fe1Y₂O₃ plates. The effect these coatings had on cell performance was studied. For example, an 8 mol % YSZ tubular based SOFC was used in combination with an Ag-La₀.₈Sr₀.₂CrO₃ coated Cr5Fe1Y₂O₃ metal plate. At 900°C and 0.7 V, using H₂ bubbled through H₂O at 25 cm³ min⁻¹, a current density of 40 mA cm⁻² was achieved for the coated Cr5Fe1Y₂O₃ as compared to 16 mA cm⁻² for the non-coated. Dense (98% relative to theoretical), gas-tight, Ce₀.₈Gd₀.₂O₁.₉ electrolyte tubes were successfully fabricated using an extrusion process. Processing parameters, such as the modification of the Ce₀.₈Gd₀.₂O₁.₉ particle size by heat-treatment and addition of the correct proportions of organic extrusion aids, were shown to determine the quality of the final sintered tube. Electrodes were added to the electrolyte tube and the cell tested. At 600°C, using H₂ bubbled through H₂O at 25 cm³ min⁻¹, an open circuit voltage of 0.911 V was achieved. The chemical compatibility of the Ce₀.₈Gd₀.₂O₂ electrolyte with perovskite current collect coatings and Cr₂O₃ (the scale formed on the surface of Cr-based metal interconnects) was studied. The Cr₂O₃ and phase pure (La,Sr)CrO₃ perovskite were shown to be chemically compatible with the electrolyte at typical operating temperatures, and at co-firing temperatures. Second phases associated with the perovskite coatings were, however, shown to react with Ce₀.₈Gd₀.₂O₁.₉ at co-firing temperatures, digesting and reacting with the electrolyte. The reaction products formed were considered to be Cr based perovskite phases. This thesis concludes with recommendations for future study.
dc.format.mimetypeapplication/pdf
dc.language.isoen
dc.publisherThe University of Waikato
dc.rightsAll items in Research Commons are provided for private study and research purposes and are protected by copyright with all rights reserved unless otherwise indicated.
dc.titleFabrication and properties of thin-walled SOFC electrolyte tubes
dc.typeThesis
thesis.degree.grantorThe University of Waikato
thesis.degree.levelDoctoral
thesis.degree.nameDoctor of Philosophy (PhD)
dc.date.updated2022-08-18T03:15:37Z
pubs.place-of-publicationHamilton, New Zealanden_NZ


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record