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      Synthesis and structure of the amidate-bridged platinum-uranium bimetallic complex [Pt{NC(O)CH₂CH₂}₂(PPh₃)₂].UO₂(NO₃)₂

      Henderson, William; Oliver, Allen G.; Rickard, Clifton E.F.
      DOI
       10.1016/S0020-1693(00)00186-9
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      Henderson, W., Oliver, A. G., & Rickard, C. E. F. (2000). Synthesis and structure of the amidate-bridged platinum-uranium bimetallic complex [Pt{NC(O)CH₂CH₂}₂(PPh₃)₂].UO₂(NO₃)₂. Inorganica Chimica Acta, 307(1/2), 144-148.
      Permanent Research Commons link: https://hdl.handle.net/10289/3421
      Abstract
      The reaction of the β-propiolactam-derived platinum(II) amidate complex [Pt{NC(O)CH₂CH₂}₂(PPh₃)₂]with uranyl nitrate gives the coordination complex [Pt{NC(O)CH₂CH₂}₂(PPh₃)₂].UO₂(NO₃)₂, which was characterised by a single-crystal X-ray diffraction study. The lactam carbonyl groups are coordinated to the linear uranyl group, forming an eight-membered ring, with the uranium also having two bidentate nitrates, completing a hexagonal bipyramidal coordination geometry. The platinum and uranium coordination planes are almost perpendicular, at an angle of 85.4(1)°.
      Date
      2000
      Type
      Journal Article
      Publisher
      ELSEVIER SCIENCE SA
      Collections
      • Science and Engineering Papers [3019]
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